Crack propagation in the hydrogeninduced brittle fracture. Sulphide stress cracking ssc resistance mill guaranteed. Miura m and ogawa k, hydrogen embrittled cracking in duplex stainless steel weld metal, iiw doc ix146187. Lastly, using post weld heat treatment to bake out the hydrogen is also an option. The use of thermal blankets to further slow down the cooling rate is also helpful. Hydrogen induced crack resistant steel plates exporter, hic. Another type of hydrogen corrosion, stressorientated hydrogen induced cracking sochic, is normally found in the base metal adjacent to the weld, where the stress point is highest due to the internal pressure of the. Nako2 hydrogen induced cracking hic remains a prominent issue for oil and gas exploration in challenging environments.
Brown mcfarlane offers the widest range of carbon and stainless steel plate, available exstock. Pdf sulfide stress corrosion cracking and hydrogen induced. Since catastrophic failure is unacceptable in engineering, hydrogens detrimental effects need to be reduced as much as possible. Hydrogen induced cracking safe materials operating limits.
The most common grades of hic resistant steel plate is a516 to asmeastm standards. May 22, 2018 hic, hydrogen induced cracking, hydrogen induced cracking test, ultrasonic, cscan, cscan. A summary of the features of brown mcfarlanes range of hic plates. Lippold abstract an implant test was used to investigate the effect of welding conditions on the. Hydrogeninduced cracking an overview sciencedirect topics. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process environments. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogeninduced cracking hic.
Hydrogen induced cracking steel features, applications. Hydrogen induced crack resistant steel plates brown mcfarlane. Hydrogen traps and hydrogen induced cracking in 20crmo. The production process for hic resistant steels includes critical desulphurization techniques including the injection of magnesium and stirring by bottom. Crystallographic character of grain boundaries resistant to. Brown mcfarlane holds an extensive stock range of hydrogen induced crack resistant steel plates or hic plates as they are more commonly known. Hydrogeninduced stress cracking of swaged super duplex. Hydrogen materials consortium department of energy. The microstructure of the steel also exhibited nitride precipitates within the ferrite grains. Hydrogen induced cracking hic in the oil and gas industry.
Thus, the present work aims to study the resistance to hydrogeninduced cracking of api 5l b and x52ms steels in 177a, 177b, and 284b nace solutions. Hic resistant steel plates are available as astmasme asa 516 grades 60, 65, and 70. Hic test, hydrogen induced cracking test, step wise cracking. Piping and vessels were fabricated by non hic resistant material. Hydrogen induced crack resistant steel plate ns energy. Crystallographic texture control helps improve pipeline steel.
Evaluation of hydrogeninduced cracking resistance of the in625. Astmasme asa 516 606570 in accordance with masterhic 51015 hic resistant steel for pressure equipment in sour service. In the pursuit to process metals and alloys that are resistant to hydrogen damage, there are. Double influence of hydrogen on fatigue crack growth in. Hydrogen induced cracking is a form of planar cracking when atomic hydrogen diffuses into the carbon or low alloy steel plate. Sulfide stress cracking is the worst type of corrosion in the presence of hydrogen sulfide. Sulfide stress cracking mostly occurs in very highly acidic environments. Customers can easily avail this pipe from us at nominal rates. Hic testing is recommended to evaluate the resistance of pipeline and pressure vessel plate steels to hydrogen induced cracking corrosion caused by hydrogen absorption from aqueous sulfide corrosion.
Nace mr0175iso 151562 standard provides test conditions and acceptance criteria to evaluate the resistance of carbon and low alloy steels to hydrogen induced cracking hic. The ssc of medium strength steels has been a continuing source of trouble in the oil fields, and from these troubles has evolved in international standards 6. May 19, 2009 susceptibility to hydrogen blistering and hydrogen induced cracking can be apportioned to the quality of the steel plate used. The hic may promote one mode of fracture in an alloy rather than another form normally observed in benign environments. Hydrogen embrittlement he of engineering alloys is characterized by a loss of ductility and sudden, often unexpected fracture 1 causing an ever widening spectrum of. To understand the mechanics of hydrogen induced damage leading to crack nucleation in metals and develop a framework that can quantify the cycles required for crack. Additionally, hydrogen atoms diffuse through metals and coalesce. Hydrogen blistering a special case of hydrogen damage is known as hydrogen blistering. It is shown that the character and intensity of hydrogen induced effects depend on temperature and loading amplitude. It will generally be certified to grades 60, 65 and 70 so one plate can meet the requirements for any of.
The process is one of crack initiation and slow crack growth, followed by cataclysmic crack propagation fracture. The macroscopic features of hydrogen induced static fatigue have been identified. It is a complex process that is not completely understood because of the variety and complexity of mechanisms that can lead to embrittlement. Hydrogen induced cracking hic represents a common challenge, especially in the petroleum and refinery industry where the purity and overall quality of the steel is of paramount importance. Cold cracking is also called hydrogen induced cracking or simply hydrogen cracking because hydrogen trapped in the weld and heataffected zone is responsible for this type of cracking. Hydrogen induced cracking steel features, applications and. Plates from stock or mill production are supplied from 6mm to 105mm thick, up to 4,000mm wide, and up to 14,000mm long.
Roles of microalloying elements in hydrogen induced cracking resistant property of hsla steels hy. Heataffected zone hydrogen induced cracking tendency of a blast resistant steel the effect of heat input and preheat on the haz hydrogen induced cracking tendency of ba160 was evaluated by the implant test by x. Hydrogen induced cracking hic assessment in a gas processing plant. The blistering damage tends to form parallel to the surface and to the direction of hoop stress. Wet hydrogen sulfide h2s cracking inspectioneering. Hydrogen induced cracking of subsea duplex stainless steel twi. Hic is often fairly innocuous but not always, while sohic is a type of cracking that can easily lead to failure. It can occur when carbonsteel equipment becomes exposed to wet h 2 s service environments, and it can come in several different forms. We will now go over how to prevent hic from happening. Hydrogeninduced cracking hic susceptibility tests, hydrogen permeation tests and the electron backscatter diffraction ebsd measurements were used to study the effect of nb on the hic resistance of the highstrength lowalloy hsla steel. Effect of welding parameters on the heataffected zone.
Brown mcfarlane supplies pressure vessel steel plates that are manufactured and tested to be resistant to hydrogen induced cracking hic. Hydrogen cracking of ferriticaustenitic stainless steel weld. Nace tm02842003 nace international resistance to hydrogeninduced cracking. Hydrogen induced cracking is associated with absorption of hydrogen and a delayed time to failure incubation time during which hydrogen diffuses into regions of high triaxial stress. Abstract a recent subsea failure of two subsea connectors made of uns s32760, a 25 wt% cr super duplex stainless steel, led to an extensive root cause failure analysis. Increasing pressure to 100bara gave a modest decrease in threshold stress for hisc crack propagation but had no effect on crack initiation. Sulfide stress cracking is a function of hydrogen sulfide concentration as low as ppm, hydrogen sulfide partial pressure, stresses, material yield strength, temperature and ph. Hydrogen induced crack resistant steel plates are available in varied sizes, shapes and dimensions to suit the requirement of clients. An appliedstress can cause these hydride particles to align. If you recall, we mentioned you need all three factors to be present in order to have hic. This can occur during elevatedtemperature thermal treatments and in service during electroplating, contact with maintenance chemicals, wet h2s, corrosion reactions, cathodic protection, and operating in highpressure hydrogencontaining environments. Aug 23, 2018 hydrogen embrittlement he of engineering alloys is characterized by a loss of ductility and sudden, often unexpected fracture 1 causing an ever widening spectrum of component failures 2. These provided long crack paths, uninhibited by austenite which would block the. Hydrogeninduced cracking hic in steel is a risk problem when steels are charged with hydrogen in service as in various hydrogen sulfide environments like sour oil and gas wells and some power plants.
China hic steel plate manufacturer, hic steel plate factory. The most common forms of wet h 2 s cracking are hydrogen induced cracking hic, stressoriented hydrogen induced cracking sohic, and sulfide stress cracking ssc. Preventing hydrogen induced cracking welding answers. Model of parameters controlling resistance of pipeline. Production of hic resistant steels total materia article. Identify hydrogen resistant, highstrength ferritic steel microstructures objective. A recent subsea failure of two subsea connectors made of uns s32760, a 25 wt% cr super duplex. Hydrogen induced craking hic, also referred to as hydrogen stress cracking or static fatigue, is a typical form of hydrogen embrittlement. Specimens containing a high hydrogen concentration in the surface layers were examined. Direct evidence has been obtained of crack initiation and propagation along dislocation slip bands leading to sample fracture.
Hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. After cathodic hydrogen charging, hydrogen induced cracking hic was detected in the hotrolled recrystallized steels, whereas the cold and warmrolled recrystallized steels proved resistant to this damage. Stress corrosion cracking and hydrogen embrittlement of high. Combatting the problem of hydrogen induced cracking in sour service, hic steel plate is carbon steel plates which are tested to assess the susceptibility of the material to hydrogen induced cracking. Hydrogen induced cracking hic occurs when carbon steel is exposed to hydrogen sulphide h 2 s and is the direct result of electrochemical corrosion reactions between the sour service or wet h 2 s environment. Hydrogen cracking of ferriticaustenitic stainless steel. Hydrogen induced cracking in austeniticferritic duplex stainless steels, proc conf. Aug 01, 2019 hydrogen induced stress cracking of swaged super duplex stainless steel subsea components, corrosion 757. With the increasingly serious problem of hydrogen sulfide corrosion, the development of antisulfur seamless pipeline is imminent, and the performance of sulfur resistant is the key. Hydrogen induced cracking hydrogen induced cracking hic when corrosion of steel occurs in an acid solution e. Thickness up to 200mm, plate sizes up to 12000mm x 4000mm. It 5has been shown that crack susceptible and crack resistant steels and other. Hydrogen induced crack resistant steel plates suppliers.
Hydrogeninduced crack growth rate in steel plates exposed. Eckhardt steel and alloys is the leading supplier and exporter of astm a516 hic resistant steel plates, hydrogen induced crack resistant steel plates, hic resistant steel plates. Hic steel plate specifications available from stock. The highstrength, precipitationhardening, stain less steels have varying degrees of resistance to stresscorrosion cracking and hydrogen embrittlement, depending upon strength level and heattreating pro. Dec 21, 2016 hydrogen induced cracking hic there are a variety of forms of wet h2s cracking. Inquiry for pricelist for inquiries about our products or pricelist, please leave your email to us and we will be in touch within 24 hours. Liou 1 steel and aluminum research and development department, china steel corp.
This occurs when steel is rapidly cooled and allowed to form martensite. Understanding and mitigating hydrogen embrittlement of steels. The most common grades of hydrogen induced crack resistant steel plates is a516 to asmeastm standards. Wet h2s service what are the requirements for steel plate. Hydrogen induced crack resistant steel plates exporter. From our last post we know that most materials contain traces of hydrogen, but the hydrogen associated with hic is a product of the welding process. Hic test specimens are machined with thickness of 530mm, width 20mm, and length of 100mm is suitable for testing as per the nace standard. Achievement of good hic resistance requires desulfurization to low levels. A mathematical model was proposed for determining the crack growth rate of hydrogen induced cracking hic in steel plates exposed to a sour gas. Hydrogen enhanced dislocation emission proposes that hydrogen is adsorbed onto to the surface and allows dislocations to be generated at lower stress levels thus increasing the level of localised plasticity at the tip of a crack allowing it to propagate more freely. Insitu observation of hydrogen induced crack initiation. Brown mcfarlane is an industeelauthorised stock supplier of carelso hic. For the crack resistance threshold, we discovered the phenomenon of temperature inversion of these.
The effect of microstructure on hic is discussed for steels having two different levels of nonmetallic inclusions. The use of steel pressure vessels in industries such as oil and gas processing requires a robust steel which is resilient to the long term corrosive effects of hydrogen sulphide in sour service applications. Hydrogen induced cracking resistance of seamless tube material. Hydrogen induced crack resistant steel plates is used by boiler makers and fabricators when hydrogen induced cracking is a big risk. Hydrogen pressure, assisted by hydrogen embrittlement then can cause cracks to appear without the requirement for any external stresses.
Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process. Hic resistant steel plates, hydrogen induced crack, hic. It involves atomic hydrogen, which is the smallest atom, that diffuses into a metallic structure. Hydrogen induced cracking is a mechanical fracture caused by penetration and diffusion of atomic hydrogen into the internal structure of steel, which changes into molecular. This assessment discusses hic in light of hydrogen transport through pipeline steel microstructures and crack initiation and propagation. This is a problem commonly found in wet h2ssour service operating environments such as in the oil, gas and petrochemical industry. Hydrogeninduced cracking results from atomic hydrogen being absorbed by solid metals. The hydrogen is first produced as hydrogen atoms h which normally combine rapidly to form hydrogen molecules h 2. Hydrogen induced crack resistant steel plates brown. Effect of nb on the hydrogeninduced cracking of high.
Hydrogen induced cracking of subsea duplex stainless steel. Hydrogen induced cracking hic is a failure mechanism resulting in sudden exposures and cracks due to growing laminations inside the base material and welds. Steels with different microstructures were produced by a thermomechanically controlled process tmcp from two different heats. Hydrogen induced crack initiation in a nickelbased superalloy was studied via insitu scanning electron microscopy observation under slow strain rate loading. Converting hydrogen flux to corrosion rates and hydrogen. Hic resistant steel plate is used by boiler makers and fabricators when hydrogen induced cracking is a big risk. The failure mechanism induced by hydrogeninduced cracking hic in a inconel 625 coating cmn steel has not been extensively investigated in the past. Hic test apparatus is supplied with essential spares for uninterrupted long term testing. Hydrogen induced cracking test apparatus is rectangular provided with ready to use connections fittings. Hydrogeninduced cracking hic has been studied phenomenologically. The presence of hydrogen atoms in a metal degrades some of its mechanical properties, especially its ductility, leading in some cases to embrittlement. Processes or conditions involving wet hydrogen sulfide, i. Jun 03, 2018 hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. Hydrogen induced corrosion pages 1 8 text version fliphtml5.
Effect of microstructure on hydrogeninduced cracking of. In the case of a crystal lattice becoming saturated or coming into contact with atomic hydrogen, many alloys and metals may. Duplex stainless steels 86, the hague, the netherlands, 2628 october 1986, nederlands institut voor latechniek, 1986, paper 26, 268279. Hydrogen induced stress cracking hisc resistance and. Prevention of hydrogen corrosion in the pursuit to process metals and alloys that are resistant to hydrogen damage, there aretwo forms of prevention. More resistant materials, such as inconels and hastelloys often employed to combat hic, can become susceptible under the combined influence of severe cold work, the presence of hydrogen recombination poisons, and a direct current from the galvanic couple due to electrical contact with a more anodic member. The model assumes that the extension of an embedded circular crack results from accumulation of internal hydrogen pressure that produces a rise of the stress intensity factor in excess of the plane. It is characterized by the brittle fracture of a normally ductile alloy under sustained load in the presence of hydrogen. Prior to 2003, hydrogen induced cracking hic testing was not incorporated into nace mr0175 iso 15156 and generally was not required for mildly sour environments i.
Hydrogen induced crack resistant steel plates suppliers co. Hydrogen induced cracking resistance of seamless tube material seamless pipeline is mainly used for conveying highpressure oil and gas near the wellhead. Eckhardt steel and alloys ensures on time delivery for all its products with best price. Hydrogen induced crack hic resistant steel plate range tested to nace tm 028403 solution a. Hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high concentration of hydrogen. A comparative study of hydrogeninduced cracking resistances of. Particularly common to the oil and gas industry where the use of. A quantitative model of hydrogen induced grain boundary. Journal of iron and steel research international 22. Wet h 2 s corrosion can be a particularly dangerous form of corrosion because damage caused by it takes place on the interior of. O ur last post factors influencing hydrogen induced cracking went over the factors that contribute to hydrogen induced cracking. Hic test, hydrogen induced cracking test, step wise.
Hydrogen induced cracking hic is most commonly encountered in steels but other metals are susceptible, as shown in table 33. Vargas pm, wastberg s and woollin p, stress based design guidelines for hydrogen induced stress cracking hisc avoidance in duplex materials, proc conf omae 200979504. Hydrogen flux and corrosion rate measurements on hydrogen induced cracking susceptible and resistant a516 steels in various sour environments, corrosion 2010, paper 10179, conf. The path of crack growth in hydrogen embrittled steels is a function of the stress intensity factor, k mpavm. The buildup of hydrogen gas then increases the pressure beneath the surface of the metal to form blisters. Hydrogeninduced cracking hic is still a challenging issue that requires careful.
Roles of microalloying elements in hydrogen induced cracking. All different forms of corrosion are explained by nace certified. Hydrogen induced stress cracking hisc resistance and improvement. An electrical resistance method was developed to permit analysis of the crack growth kinetics. Sulfide stress corrosion cracking and hydrogen induced cracking of a216wcc wellhead flow control valve body article pdf available in case studies in engineering failure analysis. Hydrogen induced stress cracking of swaged super duplex stainless steel subsea components, corrosion. Efc publication 17, 2nd edition, corrosion resistant alloys for oil and gas production. Sandia national laboratories is a multi program laboratory managed and operated by sandia corporation, a wholly owned subsidiary of lockheed martin corporation, for the u. Unstressed test specimens are exposed to a solution at temperature of. Hic steel hydrogen induced cracking supplier company. Embrittlement can be reversed with treatment that effectively rids the metal.
Hydrogeninduced degradation and all phenomena associated with its. Crystallographic character of grain boundaries resistant. Hydrogen induced cracking hic remains a prominent issue for oil and. Hydrogen blistering occurs when hydrogen atoms diffuse into the steel, and hydrogen gas nucleates at internal defects and inclusions, forming voids which eventually generate enough pressure to locally rupture the metal.